| Time | Status | Match | FT | H1 | Stats |
| 04/10/2013 20:00 |
(FT) | Villarreal[4] Granada[16] |
3 0 |
1 0 |
MF | ME |
| 04/10/2013 22:00 |
(FT) | Malaga[8] Osasuna[19] |
0 1 |
0 1 |
MF | ME |
| 05/10/2013 16:00 |
(FT) | Elche[17] Espanyol[7] |
2 1 |
1 0 |
MF | ME |
| 05/10/2013 17:59 |
(FT) | Rayo Vallecano[20] Real Sociedad[9] |
1 0 |
0 0 |
MF | ME |
| 05/10/2013 20:00 |
(FT) | Levante[11] Real Madrid[3] |
2 3 |
0 0 |
MF | ME |
| 05/10/2013 22:00 |
(FT) | Barcelona[1] Valladolid[14] |
4 1 |
1 1 |
MF | ME |
| 06/10/2013 12:00 |
(FT) | Atletico Madrid[2] Celta Vigo[14] |
2 1 |
1 0 |
MF | ME |
| 06/10/2013 17:00 |
(FT) | Sevilla[13] Almeria[18] |
2 1 |
1 1 |
MF | ME |
| 06/10/2013 19:00 |
(FT) | Getafe[8] Real Betis[11] |
3 1 |
3 0 |
MF | ME |
| 06/10/2013 21:00 |
(FT) | Athletic Bilbao[5] Valencia[6] |
1 1 |
0 1 |
MF | ME |