| Time | Status | Match | FT | H1 | Stats |
| 14/09/2013 16:00 |
(FT) | Atletico Madrid[2] Almeria[14] |
4 2 |
2 1 |
MF | ME |
| 14/09/2013 17:59 |
(FT) | Levante[10] Real Sociedad[8] |
0 0 |
0 0 |
MF | ME |
| 14/09/2013 20:00 |
(FT) | Barcelona[1] Sevilla[15] |
3 2 |
1 0 |
MF | ME |
| 14/09/2013 22:00 |
(FT) | Villarreal[3] Real Madrid[4] |
2 2 |
1 1 |
MF | ME |
| 15/09/2013 12:00 |
(FT) | Granada[9] Espanyol[6] |
0 1 |
0 0 |
MF | ME |
| 15/09/2013 17:00 |
(FT) | Getafe[19] Osasuna[20] |
2 1 |
1 1 |
MF | ME |
| 15/09/2013 19:00 |
(FT) | Malaga[17] Rayo Vallecano[13] |
5 0 |
2 0 |
MF | ME |
| 15/09/2013 21:00 |
(FT) | Real Betis[18] Valencia[12] |
3 1 |
3 0 |
MF | ME |
| 16/09/2013 20:00 |
(FT) | Elche[16] Valladolid[11] |
0 0 |
0 0 |
MF | ME |
| 16/09/2013 22:00 |
(FT) | Athletic Bilbao[5] Celta Vigo[7] |
3 2 |
1 1 |
MF | ME |