| Time | Status | Match | FT | H1 | Stats |
| 24/01/2014 21:00 |
(FT) | Celta Vigo[16] Real Betis[20] |
4 2 |
3 1 |
MF | ME |
| 25/01/2014 16:00 |
(FT) | Real Madrid[2] Granada[10] |
2 0 |
0 0 |
MF | ME |
| 25/01/2014 18:00 |
(FT) | Valladolid[18] Villarreal[5] |
1 0 |
1 0 |
MF | ME |
| 25/01/2014 20:00 |
(FT) | Valencia[9] Espanyol[8] |
2 2 |
2 2 |
MF | ME |
| 25/01/2014 22:00 |
(FT) | Sevilla[7] Levante[11] |
2 3 |
1 1 |
MF | ME |
| 26/01/2014 12:00 |
(FT) | Almeria[17] Getafe[12] |
1 0 |
0 0 |
MF | ME |
| 26/01/2014 16:59 |
(FT) | Osasuna[13] Athletic Bilbao[5] |
1 5 |
1 2 |
MF | ME |
| 26/01/2014 19:00 |
(FT) | Rayo Vallecano[19] Atletico Madrid[2] |
2 4 |
1 3 |
MF | ME |
| 26/01/2014 21:00 |
(FT) | Barcelona[1] Malaga[14] |
3 0 |
1 0 |
MF | ME |
| 27/01/2014 22:00 |
(FT) | Real Sociedad[6] Elche[15] |
4 0 |
2 0 |
MF | ME |