| Time | Status | Match | FT | H1 | Stats |
| 04/04/2014 21:00 |
(FT) | Almeria[16] Osasuna[17] |
1 2 |
0 2 |
MF | ME |
| 05/04/2014 16:00 |
(FT) | Atletico Madrid[1] Villarreal[7] |
1 0 |
1 0 |
MF | ME |
| 05/04/2014 17:59 |
(FT) | Barcelona[2] Real Betis[20] |
3 1 |
1 0 |
MF | ME |
| 05/04/2014 20:00 |
(FT) | Real Sociedad[6] Real Madrid[3] |
0 4 |
0 1 |
MF | ME |
| 05/04/2014 22:00 |
(FT) | Rayo Vallecano[14] Celta Vigo[11] |
3 0 |
1 0 |
MF | ME |
| 06/04/2014 12:00 |
(FT) | Malaga[12] Granada[13] |
4 1 |
2 0 |
MF | ME |
| 06/04/2014 17:00 |
(FT) | Elche[15] Getafe[16] |
1 0 |
0 0 |
MF | ME |
| 06/04/2014 19:00 |
(FT) | Sevilla[5] Espanyol[9] |
4 1 |
2 0 |
MF | ME |
| 06/04/2014 21:00 |
(FT) | Valladolid[19] Valencia[8] |
0 0 |
0 0 |
MF | ME |
| 07/04/2014 22:00 |
(FT) | Levante[10] Athletic Bilbao[4] |
1 2 |
0 2 |
MF | ME |