| Time | Status | Match | FT | H1 | Stats |
| 25/09/2021 14:00 |
(FT) | Alaves[20] Atletico Madrid[1] |
1 0 |
1 0 |
MF | ME |
| 25/09/2021 16:15 |
(FT) | Valencia[3] Athletic Bilbao[6] |
1 1 |
0 0 |
MF | ME |
| 25/09/2021 18:30 |
(FT) | Sevilla[7] Espanyol[17] |
2 0 |
1 0 |
MF | ME |
| 25/09/2021 21:00 |
(FT) | Real Madrid[2] Villarreal[14] |
0 0 |
0 0 |
MF | ME |
| 26/09/2021 14:00 |
(FT) | Mallorca[12] Osasuna[11] |
2 3 |
2 1 |
MF | ME |
| 26/09/2021 16:15 |
(FT) | Barcelona[8] Levante[16] |
3 0 |
2 0 |
MF | ME |
| 26/09/2021 18:30 |
(FT) | Rayo Vallecano[6] Cadiz[13] |
3 1 |
2 1 |
MF | ME |
| 26/09/2021 18:30 |
(FT) | Real Sociedad[4] Elche[15] |
1 0 |
0 0 |
MF | ME |
| 26/09/2021 21:00 |
(FT) | Real Betis[8] Getafe[19] |
2 0 |
1 0 |
MF | ME |
| 27/09/2021 21:00 |
(FT) | Celta Vigo[17] Granada[18] |
1 0 |
0 0 |
MF | ME |