| Time | Status | Match | FT | H1 | Stats |
| 04/02/2022 21:00 |
(FT) | Getafe[16] Levante[20] |
3 0 |
2 0 |
MF | ME |
| 05/02/2022 14:00 |
(FT) | Elche[15] Alaves[19] |
3 1 |
0 1 |
MF | ME |
| 05/02/2022 16:15 |
(FT) | Mallorca[17] Cadiz[18] |
2 1 |
1 1 |
MF | ME |
| 05/02/2022 18:30 |
(FT) | Celta Vigo[12] Rayo Vallecano[8] |
2 0 |
1 0 |
MF | ME |
| 05/02/2022 21:00 |
(FT) | Osasuna[11] Sevilla[2] |
0 0 |
0 0 |
MF | ME |
| 06/02/2022 14:00 |
(FT) | Valencia[10] Real Sociedad[6] |
0 0 |
0 0 |
MF | ME |
| 06/02/2022 16:15 |
(FT) | Barcelona[5] Atletico Madrid[4] |
4 2 |
3 1 |
MF | ME |
| 06/02/2022 18:30 |
(FT) | Real Betis[3] Villarreal[7] |
0 2 |
0 1 |
MF | ME |
| 06/02/2022 21:00 |
(FT) | Real Madrid[1] Granada[14] |
1 0 |
0 0 |
MF | ME |
| 07/02/2022 21:00 |
(FT) | Athletic Bilbao[9] Espanyol[13] |
2 1 |
2 1 |
MF | ME |