| Minute | Score | Villarreal | Espanyol | |
| 5' | 0 - 1 |  Lopez D. (Naldo) |
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| 24' | 0 - 1 |  Vila D. |
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| 32' | 0 - 1 | Lopez J. |
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| 41' | 0 - 1 | Trigueros M. |
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| 47' | 0 - 2 | De Tomas R. |
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| 54' | 0 - 2 | Gomez M. (Zambo Andre-Frank) |
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| 59' | 0 - 2 |  Lopez J. |
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| 62' | 1 - 2 | Cazorla S. (Penalty) |
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| 63' | 1 - 2 | Sanchez V. (Calleri J.) |
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| 69' | 1 - 2 | Pena R. (Mario Gaspar) |
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| 75' | 1 - 2 | Calero F. (Melendo O.) |
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| 76' | 1 - 2 | De Tomas R. |
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| 80' | 1 - 2 | Ontiveros P. J. (Moreno A.) |
