| Time | Status | Match | FT | H1 | Stats |
| 29/10/2019 19:00 |
(FT) | Alaves[14] Atletico Madrid[5] |
1 1 |
0 0 |
MF | ME |
| 29/10/2019 21:15 |
(FT) | Barcelona[1] Valladolid[12] |
5 1 |
3 1 |
MF | ME |
| 30/10/2019 19:00 |
(FT) | Real Sociedad[5] Levante[12] |
1 2 |
0 2 |
MF | ME |
| 30/10/2019 19:00 |
(FT) | Valencia[11] Sevilla[7] |
1 1 |
0 1 |
MF | ME |
| 30/10/2019 20:00 |
(FT) | Athletic Bilbao[9] Espanyol[20] |
3 0 |
2 0 |
MF | ME |
| 30/10/2019 21:00 |
(FT) | Real Betis[18] Celta Vigo[17] |
2 1 |
1 0 |
MF | ME |
| 30/10/2019 21:15 |
(FT) | Real Madrid[2] Leganes[19] |
5 0 |
3 0 |
MF | ME |
| 31/10/2019 19:00 |
(FT) | Eibar[16] Villarreal[6] |
2 1 |
0 0 |
MF | ME |
| 31/10/2019 19:00 |
(FT) | Mallorca[15] Osasuna[13] |
2 2 |
1 0 |
MF | ME |
| 31/10/2019 21:15 |
(FT) | Getafe[9] Granada[1] |
3 1 |
2 0 |
MF | ME |