| Time | Status | Match | FT | H1 | Stats |
| 23/10/2020 21:00 |
(FT) | Elche[12] Valencia[13] |
2 1 |
2 0 |
MF | ME |
| 24/10/2020 16:00 |
(FT) | Barcelona[9] Real Madrid[3] |
1 3 |
1 1 |
MF | ME |
| 24/10/2020 18:30 |
(FT) | Osasuna[11] Athletic Bilbao[14] |
1 0 |
0 0 |
MF | ME |
| 24/10/2020 18:30 |
(FT) | Sevilla[10] Eibar[15] |
0 1 |
0 1 |
MF | ME |
| 24/10/2020 21:00 |
(FT) | Atletico Madrid[8] Real Betis[7] |
2 0 |
0 0 |
MF | ME |
| 25/10/2020 14:00 |
(FT) | Valladolid[19] Alaves[18] |
0 2 |
0 0 |
MF | ME |
| 25/10/2020 16:00 |
(FT) | Cadiz[5] Villarreal[2] |
0 0 |
0 0 |
MF | ME |
| 25/10/2020 18:30 |
(FT) | Getafe[4] Granada[6] |
0 1 |
0 1 |
MF | ME |
| 25/10/2020 21:00 |
(FT) | Real Sociedad[1] SD Huesca[16] |
4 1 |
1 0 |
MF | ME |
| 26/10/2020 21:00 |
(FT) | Levante[20] Celta Vigo[17] |
1 1 |
0 0 |
MF | ME |