| Time | Status | Match | FT | H1 | Stats |
| 25/08/2012 19:00 |
(FT) | Real Sociedad Celta Vigo |
2 1 |
0 0 |
MF | ME |
| 25/08/2012 21:00 |
(FT) | Espanyol Zaragoza |
1 2 |
1 0 |
MF | ME |
| 25/08/2012 21:00 |
(FT) | Real Betis Rayo Vallecano |
1 2 |
1 1 |
MF | ME |
| 25/08/2012 23:00 |
(FT) | Malaga Mallorca |
1 1 |
0 0 |
MF | ME |
| 26/08/2012 19:00 |
(FT) | Osasuna Barcelona |
1 2 |
1 0 |
MF | ME |
| 26/08/2012 21:00 |
(FT) | Getafe Real Madrid |
2 1 |
0 1 |
MF | ME |
| 26/08/2012 21:00 |
(FT) | Granada Sevilla |
1 1 |
1 1 |
MF | ME |
| 26/08/2012 23:00 |
(FT) | Valencia Deportivo La Coruna |
3 3 |
3 1 |
MF | ME |
| 27/08/2012 20:00 |
(FT) | Valladolid Levante |
2 0 |
1 0 |
MF | ME |
| 27/08/2012 22:00 |
(FT) | Atletico Madrid Athletic Bilbao |
4 0 |
2 0 |
MF | ME |