| Time | Status | Match | FT | H1 | Stats |
| 11/03/2006 18:00 |
(FT) | Espanyol Celta Vigo |
2 0 |
2 0 |
MF | ME |
| 11/03/2006 20:00 |
(FT) | Deportivo La Coruna Real Sociedad |
0 1 |
0 0 |
MF | ME |
| 11/03/2006 22:00 |
(FT) | Valencia Real Madrid |
0 0 |
0 0 |
MF | ME |
| 12/03/2006 16:59 |
(FT) | Alaves Sevilla |
2 1 |
2 1 |
MF | ME |
| 12/03/2006 16:59 |
(FT) | Athletic Bilbao Cadiz |
1 0 |
0 0 |
MF | ME |
| 12/03/2006 16:59 |
(FT) | Real Betis Malaga |
1 1 |
1 0 |
MF | ME |
| 12/03/2006 16:59 |
(FT) | Mallorca Villarreal |
1 1 |
1 1 |
MF | ME |
| 12/03/2006 16:59 |
(FT) | Zaragoza Getafe |
1 2 |
1 1 |
MF | ME |
| 12/03/2006 19:00 |
(FT) | Atletico Madrid Racing de Santander |
2 1 |
0 0 |
MF | ME |
| 12/03/2006 21:00 |
(FT) | Osasuna Barcelona |
2 1 |
1 0 |
MF | ME |