| Time | Status | Match | FT | H1 | Stats | |
| 04/10/2006 19:30 |
(FT) | CD Pena Sport[5] Alcoyano[16] |
2 0 |
2 0 |
MF | ME | |
| 04/10/2006 20:00 |
(FT) | CF Badalona[2] Universidad Las Palmas[13] |
0 0 |
0 0 |
MF | ME | |
| 90 minute[0-0],120 minute[1-1],Penalty Kick[7-6] | ||||||
| 04/10/2006 20:30 |
(FT) | Burgos CF[7] Gimnastica Segoviana[4] |
1 1 |
0 1 |
MF | ME | |
| 90 minute[1-1],120 minute[2-2],Penalty Kick[5-6] | ||||||
| 04/10/2006 20:45 |
(FT) | CD Castellon Cadiz[15] |
1 0 |
0 0 |
MF | ME | |
| 04/10/2006 21:00 |
(FT) | Elche[20] Valladolid[22] |
0 1 |
0 0 |
MF | ME | |
| 04/10/2006 21:00 |
(FT) | Ejido[28] Alaves[18] |
1 1 |
1 1 |
MF | ME | |
| 90 minute[1-1],120 minute[1-1],Penalty Kick[4-5] | ||||||
| 04/10/2006 21:00 |
(FT) | Rayo Vallecano[9] UD Puertollano[10] |
0 0 |
0 0 |
MF | ME | |
| 90 minute[0-0],120 minute[0-0],Penalty Kick[5-4] | ||||||
| 04/10/2006 21:30 |
(FT) | Almeria[21] Malaga[17] |
0 0 |
0 0 |
MF | ME | |
| 90 minute[0-0],120 minute[0-0],Penalty Kick[4-5] | ||||||
| 04/10/2006 21:30 |
(FT) | Racing Club Portuense[6] CD Linares[1] |
0 0 |
0 0 |
MF | ME | |
| 90 minute[0-0],120 minute[1-0] | ||||||
| 04/10/2006 21:30 |
(FT) | Ecija Balompie[3] Eibar[8] |
0 0 |
0 0 |
MF | ME | |
| 90 minute[0-0],120 minute[0-0],Penalty Kick[5-4] | ||||||
| 04/10/2006 22:00 |
(FT) | Hercules CF[31] Las Palmas[19] |
2 0 |
0 0 |
MF | ME | |